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Multiple Choice Quiz



1

What is the name of the following compound?
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A)ethylmethylisopropylamine
B)ethylpropylsec-butylamine
C)ethylmethylpropylamine
D)sec-butylethylpropylamin
2

What is the name of the following compound?
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A)dimethylbenzylamine
B)N,N-dimethyltoluene
C)N,N-dimethylaniline
D)dimethylphenolamine
3

What is the name of the following compound?
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A)lithium diisopropylamine
B)lithium diisopropylamide
C)lithium diisopropylammonium
D)diisopropylamine anion
4

Which of the following amines is pyridine?
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_4a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (11.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_4b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (10.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_4c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (10.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_4d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (11.0K)</a>
5

Which of the following amines is a tertiary amine?
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_5a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_5b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_5c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_5d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
6

Which of the following aniline derivatives is the strongest base?
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_6a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_6b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_6c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_6d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
7

Which of the following compounds is most basic?
A)cyclohexylamine
B)aniline
C)p-methoxyaniline
D)p-nitroaniline
8

Supply the correct words to complete this sentence: Electron-withdrawing groups such as nitro _________ the basicity of anilines, especially when substituted _______________.
A)increase ; ortho or para
B)increase ; meta
C)decrease ; ortho or para
D)decrease ; meta
9

Which of the following compounds is the strongest acid?
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_9a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_9b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_9c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_9d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
10

Which of the following compounds has the most basic nitrogen?
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A)a
B)b
C)c
D)d
11

Which of the following alkyl halides is not a reasonable substrate for the Gabriel synthesis?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_11.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (18.0K)</a>
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_11a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (10.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_11b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_11c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (10.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_11d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
12

Predict the product of the following reaction.
Ph–CH2–CN + LiAlH4, Et2O →
A)Ph–CH2–CH2–NH2
B)N,N-dimethylaniline
C)benzyl ethyl ether
D)Ph–CH2–NH2
13

Predict the product of the following reaction.
Cyclohexanone + Et2NH + NaBH3CN, MeOH →
A)N,N-diethylaniline
B)N,N-diethylcyclohexylamine
C)3-cyanocyclohexanone
D)Et2N–CN
14

What is the sequence of reagents that will accomplish the synthesis of the following aromatic amine from benzene?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_14.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
A)CH3Cl, AlCl3; HNO3, H2SO4; H2
B)CH3Cl, AlCl3; HNO3, H2SO4; Fe, HCl; NaOH
C)HNO3, H2SO4; Fe, HCl; NaOH; CH3Cl, AlCl3
D)HNO3, H2SO4; CH3Cl, AlCl3; Fe, HCl; NaOH
15

Predict the product of the following reaction.
Et2NH + NaNO2/HCl →
A)Et3NH + + Et3N–N=O
B)Et2N–N=O
C)Et–N2+
D)Et–N=N–OH
16

Predict the product of the following reaction.
Et3N + NaNO2/HCl →
A)Et3NH+ + Et3N–N=O
B)Et2N–N=O
C)Et–N2+
D)Et–N=N–OH
17

Which will be the major product of the following reaction?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_17.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_171.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (20.0K)</a>
A)a
B)b
C)c
D)d
18

What is the product of the following synthesis?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_18.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (21.0K)</a>
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_18a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (15.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_18b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_18c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_18d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
19

What is the product of the following synthesis?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_19.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (19.0K)</a>
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_19a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_19b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_19c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (15.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_19d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (15.0K)</a>
20

How would you accomplish the following synthesis?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_20.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>
A)1. 1 eq. Br2, FeBr3
2. HNO3, H2SO4
3. H2, catalyst
4. HONO, ice bath
5. KI
B)1. Br2, FeBr3
2. HNO2, H2SO4
3. Zn Hg, HCl
4. HONO, room temperature
5. CuI
C)1. HNO3, H2SO4
2. 1 eq. Br2, FeBr3
3. Zn, HCl
4. HONO, ice bath
5. I2
D)1. HNO2, H2SO4
2. Fe, HCl
3. NaOH
4. HONO, ice bath
5. HI
6. Br2
21

How would you accomplish the following synthesis?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_21.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (16.0K)</a>
A)1. HNO3, H2SO4
2. NaOH
3. HONO, ice bath
4. Cu2O, H2O
5. NaH
6. MeBr
7. H2, catalyst
B)1. HNO2, H2SO4
2. Fe, HCl
3. NaOH
4. HONO, ice bath
5. Cu2O, H2O
6. MeONa, MeBr
C)1. Sn, HCl
2. HNO2, H2SO4
3. HONO, ice bath
4. Cu2O, H2O
5. MeONa
6. MeBr
D)1. HONO, ice bath
2. Cu2O, H2O
3. NaH
4. MeBr
5. HNO3, H2SO4
6. H2, catalyst
22

Predict the product of the following reaction.
Benzenediazonium chloride + CuCN →
A)Ph2CuCl
B)Ph–CN
C)Ph2CuLi
D)Ph–N=N–CN
23

Predict the product of the following reaction.
p-Nitroaniline + 1) NaNO2, H2SO4 2) KI →
A)p-diiodobenzene
B)p-dinitrobenzene
C)2,4-dinitroaniline
D)p-iodonitrobenzene
24

Predict the product of the following reaction.
2,4-Dibromobenzenediazonium chloride + H3PO2
A)m-dibromobenzene
B)m-bromochlorobenzene
C)m-dichlorobenzene
D)p-Br–Ph–N=N–Ph
25

Predict the product of the following reaction.
Nitrobenzene + 1) HNO3, H2SO4 2) Fe/HCl 3) NaNO2, HCl 4) Cu2O, CuCl2
A)m-dichlorobenzene
B)hydroquinone
C)resorcinol
D)catechol
26

Which reaction sequence will carry out the following tranformation?
<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_26.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (16.0K)</a>
A)1) Me2NC6H4NH2 + H2SO4 + NaNO2 2) Add product of 1 to a
B)1) a + H2SO4 + NaNO2 2) Me2NC6H4NH2
C)1) a + LiAlH4 (excess) 2) H2O, neutralize 3) H2SO4 + NaNO2 4) Me2NC6H4NH2
D)Me2NC6H4N2 , heat
27

What is the minimum structure necessary for the antibiotic activity of a sulfa drug?
A)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_27a.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
B)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_27b.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (13.0K)</a>
C)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_27c.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (12.0K)</a>
D)<a onClick="window.open('/olcweb/cgi/pluginpop.cgi?it=jpg::::/sites/dl/free/0072397462/209353/25_27d.jpg','popWin', 'width=NaN,height=NaN,resizable,scrollbars');" href="#"><img valign="absmiddle" height="16" width="16" border="0" src="/olcweb/styles/shared/linkicons/image.gif"> (14.0K)</a>







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