SEC. 2-1 CONDUCTORS
A neutral copper atom has only one
electron in its outer orbit. Since this single
electron can be easily dislodged from its
atom, it is called a free electron. Copper is
a good conductor because the slightest
voltage causes free electrons to flow from
one atom to the next.
SEC. 2-2 SEMICONDUCTORS
Silicon is the most widely used
semiconductor material. An isolated
silicon atom has four electrons in its outer
or valence orbit. The number of electrons
in the valence orbit is the key to
conductivity. Conductors have one
valence electron, semiconductors have
four valence electrons, and insulators
have eight valence electrons.
SEC. 2-3 SILICON CRYSTALS
Each silicon atom in a crystal has its four
valence electrons plus four more electrons
that are shared by the neighboring atoms.
At room temperature, a pure silicon
crystal has only a few thermally produced
free electrons and holes. The amount of
time between the creation and
recombination of a free electron and a
hole is called the lifetime.
SEC. 2-4 INTRINSIC
SEMICONDUCTORS
An intrinsic semiconductor is a pure
semiconductor. When an external voltage
is applied to the intrinsic semiconductor,
the free electrons flow toward the positive
battery terminal and the holes flow
toward the negative battery terminal.
SEC. 2-5 TWO TYPES OF FLOW
Two types of carrier flow exist in an
intrinsic semiconductor. First, there is the
flow of free electrons through larger
orbits (conduction band). Second, there is
the flow of holes through smaller orbits
(valence band).
SEC. 2-6 DOPING A
SEMICONDUCTOR
Doping increases the conductivity of a
semiconductor. A doped semiconductor is
called an extrinsic semiconductor. When
an intrinsic semiconductor is doped with
pentavalent (donor) atoms, it has more
free electrons than holes. When an
intrinsic semiconductor is doped with
trivalent (acceptor) atoms, it has more
holes than free electrons.
SEC. 2-7 TWO TYPES OF
EXTRINSIC
SEMICONDUCTORS
In an n-type semiconductor the free
electrons are the majority carriers, and the
holes are the minority carriers. In a p-type
semiconductor the holes are the majority
carriers, and the free electrons are the
minority carriers.
SEC. 2-8 THE UNBIASED DIODE
An unbiased diode has a depletion layer at
the pn junction. The ions in this depletion
layer produce a barrier potential. At room
temperature, this barrier potential is
approximately 0.7 V for a silicon diode
and 0.3 V for a germanium diode.
SEC. 2-9 FORWARD BIAS
When an external voltage opposes the
barrier potential, the diode is forwardbiased.
If the applied voltage is greater
than the barrier potential, the current is
large. In other words, current flows easily
in a forward-biased diode.
SEC. 2-10 REVERSE BIAS
When an external voltage aids the barrier
potential, the diode is reverse-biased. The
width of the depletion layer increases
when the reverse voltage increases. The
current is approximately zero.
SEC. 2-11 BREAKDOWN
Too much reverse voltage will produce
either avalanche or zener effect. Then, the
large breakdown current destroys the
diode. In general, diodes are never operated
in the breakdown region. The only
exception is the zener diode, a specialpurpose
diode discussed in a later chapter.
SEC. 2-12 ENERGY LEVELS
The larger the orbit, the higher the energy
level of an electron. If an outside force
raises an electron to a higher energy level,
the electron will emit energy when it falls
back to its original orbit.
SEC. 2-13 THE ENERGY HILL
The barrier potential of a diode looks like
an energy hill. Electrons attempting to
cross the junction need to have enough
energy to climb this hill. An external
voltage source that forward-biases the
diode gives electrons the energy required
to pass through the depletion layer.
SEC. 2-14 BARRIER POTENTIAL
AND TEMPERATURE
When the junction temperature increases,
the depletion layer becomes narrower and
the barrier potential decreases. It will
decrease approximately 2 mV for each
degree Celsius increase.
SEC. 2-15 REVERSE-BIASED
DIODE
There are three components of reverse
current in a diode. First, there is the
transient current that occurs when the
reverse voltage changes. Second, there is
the minority-carrier current, also called
the saturation current because it is
independent of the reverse voltage.
Third, there is the surface-leakage
current. It increases when the reverse
voltage increases.
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