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Solidification and Crystalline Imperfections

Chapter Objectives

  1. Describe the process of the solidification of metals distinguishing between homogeneous and heterogeneous nucleation.
  2. Describe the two energies involved in the solidification process of a pure metal, and write the equation for the total free-energy change associated with the transformation of the liquid state to solid nucleus.
  3. Distinguish between equiaxed and columnar grains and the advantage of the former over the latter.
  4. Distinguish between single crystal and polycrystalline materials and explain why single crystal and polycrystalline forms of the material have different mechanical properties.
  5. Describe various forms of metallic solid solutions and explain the differences between solid solution and mixture alloys.
  6. Classify various types of crystalline imperfections and explain the role of defects on the mechanical and electrical properties of crystalline materials.
  7. Determine the ASTM grain size number and average grain size diameter and describe the importance of grain size and grain boundary density on the behavior of crystalline materials.
  8. Learn how and why optical microscopy, SEM, TEM, HRTEM, AFM, and STM techniques are used to understand more about the internal and surface structures of materials at various magnifications.
  9. Explain, in general terms, why alloys are preferred materials over pure metals for structural applications.










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