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1 | | Consider the molecular substances I2, H2O, and C8H18. Which of them is/are soluble in CCl4? |
| | A) | only I2 |
| | B) | only H2O |
| | C) | only C8H18 |
| | D) | I2 and C8H18 |
| | E) | H2O and C8H18 |
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2 | | Which of the following is not a solution? |
| | A) | brass |
| | B) | stainless steel |
| | C) | solder |
| | D) | bronze |
| | E) | galvanized iron |
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3 | | The heat of solution of KCl is +17 kJ/mol, and the heat of hydration of 1 mole of gaseous chloride ions and 1 mole of gaseous potassium ions is -698 kJ. What is the lattice energy of potassium chloride? |
| | A) | 715 kJ/mol |
| | B) | -681 kJ/mol |
| | C) | -715 kJ/mol |
| | D) | -332 kJ/mol |
| | E) | 681 kJ/mol |
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4 | | Which of the following statements is true? |
| | A) | The solubility of all salts in water increases with temperature. |
| | B) | The solubility of all salts in water decreases with temperature. |
| | C) | The solubility of all salts in water is independent of temperature. |
| | D) | The impact of temperature on solubility depends on the individual salt. |
| | E) | Salts are insoluble in water. |
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5 | | The solubility of a gas in general _________ with increasing pressure and __________ with increasing temperature. |
| | A) | decreases, increases |
| | B) | decreases, decreases |
| | C) | remains the same |
| | D) | increases, increases |
| | E) | increases, decreases |
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6 | | The molality of a solution of ethyl alcohol, C2H5OH, in water is 0.96 mol/kg. How many grams of alcohol are dissolved in 5.98 kg of water? |
| | A) | 7.40 g |
| | B) | 287.2 g |
| | C) | 74.1 g |
| | D) | 264.7 g |
| | E) | 740 g |
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7 | | What is the mass of C12H22O11 in 60.0 mL of 0.0880 M solution? |
| | A) | 0.181 g |
| | B) | 1.81 g |
| | C) | 5.02 g |
| | D) | 5.28 g |
| | E) | none of the above |
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8 | | The alloy AlNi 120 is 13% Al, 27% Ni, and 60% Fe by weight. What is the mole percent Al for this alloy? |
| | A) | 24% |
| | B) | 13% |
| | C) | 50% |
| | D) | 32% |
| | E) | none of the above |
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9 | | What is the molarity of a solution that is 46% by mass perchloric acid (HClO4)? The density of the solution is 1.23 g/mL. |
| | A) | 5.6 M |
| | B) | 1.2 M |
| | C) | 1.7 M |
| | D) | 7.9 M |
| | E) | none of the above |
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10 | | What is the percent KCl by mass in a 3.00 molal solution? |
| | A) | 0.300% |
| | B) | 12.5% |
| | C) | 18.3% |
| | D) | 30.0% |
| | E) | none of the above |
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11 | | What is the freezing point of a solution that contains 12.0 g of glucose (C6H12O6) in 50 g of acetic acid (CH3COOH). Kf = 3.90°C/m, melting point = 16.6°C. |
| | A) | -1.41°C |
| | B) | -31.27°C |
| | C) | 16.32°C |
| | D) | 5.2°C |
| | E) | 11.4°C |
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12 | | The osmotic pressure of a solution of a synthetic polyisobutylene in benzene was determined at 25°C. A sample containing 0.30 g of solute per 125 mL of solution developed a rise of 3.4 mm at osmotic equilibrium. The density of the solution was 0.88 g/mL. What is the molar mass of the polyisobutylene? |
| | A) | 2.1 x 106 g/mol |
| | B) | 2.4 x 105 g/mol |
| | C) | 1.2 x 105 g/mol |
| | D) | 2.9 x 105 g/mol |
| | E) | 2.0 x 105 g/mol |
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13 | | The vapor pressure of pure water at 26°C is 25.21 torr. What is the vapor pressure of a solution which contains 16.0 g of glucose, C6H12O6, in 80 g of water? |
| | A) | 16.8 torr |
| | B) | 24.7 torr |
| | C) | 0.49 torr |
| | D) | 25.4 torr |
| | E) | 14.1 torr |
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14 | | The osmotic pressure of a 0.72 M solution of HCl is 35.9 atm at 18°C. Calculate the van't Hoff factor i for HCl at this concentration. |
| | A) | 67.5 |
| | B) | 4.17 |
| | C) | 33.7 |
| | D) | 0.18 |
| | E) | 2.09 |
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15 | | Which of the following pairs of phases cannot form a colloidal solution? |
| | A) | solid and liquid |
| | B) | liquid and gas |
| | C) | solid and solid |
| | D) | liquid and liquid |
| | E) | gas and gas |
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