No matter how complicated a system is, the CM moves as if all the mass of the system were concentrated to a point particle with all the external forces acting on it:
The CM of an isolated system moves at constant velocity.
Conservation of momentum is used to solve problems involving collisions, explosions, and the like. Even when external forces are acting, the momentum of the system just before a collision is nearly equal to the momentum just after if the collision interaction is brief. The impulse, and, therefore, the change in momentum of the system, is small since the time interval is small.
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