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Chemistry, 7/e
Raymond Chang, Williams College
Transition Metal Chemistry and Coordination Compounds
Self Assessment A
1
The electron configuration of a Ni
2+
ion is:
A)
[Ar]4s
2
3d
8
B)
[Ar]4s
2
3d
6
C)
[Ar]3d
8
D)
[Ar]3d
6
2
The Fe
3+
ion has _____ electrons in 3d orbitals.
A)
6
B)
5
C)
4
D)
3
E)
2
3
A ligand is
A)
a molecule or ion that has at least one lone pair of electrons.
B)
a nucleophile.
C)
a Lewis base.
D)
part of a coordination compound.
E)
All of the above.
4
In K[Cu(CN)
2
], how many 3d electrons does the copper ion have?
A)
10
B)
9
C)
8
D)
7
E)
6
5
Which of the following is a bidentate ligand?
A)
cyanide ion
B)
nitrite ion
C)
ammonia
D)
thiocyanate ion
E)
ethylenediamine
6
The correct chemical formula for tetraamminecopper(II) chloride is
A)
[Cu(NH
3
)
4
Cl]
B)
[Cu(NH
3
)
4
]Cl
2
C)
[Cu(NH
3
)
4
]Cl
3
D)
[Cu(NH
3
)
4
]Cl
E)
[Cu(NH
3
)]Cl
4
7
The best name for K[Cr(NH
3
)
2
Cl
2
(CN)
2
] is:
A)
potassium diamminedichlorodicyanochromate(III)
B)
potassium diamminedichlorodicyanochromium(III)
C)
potassium diamminedichlorochromatium(III) cyanide
D)
potassium diamminedichlorochromate(II) cyanide
E)
potassium diamminedichlorodicyanochromate(II)
8
Which of the following species could exist as a pair of isomers?
A)
[Pt(NH
3
)
3
Cl]
+
B)
[Fe(CN)
6
]
3-
C)
[Co(H
2
O)
4
Cl
2
]
+
D)
[Pt(en)Cl
2
]
E)
[Pt(NH
3
)Br
3
]
-
9
Which of the following ligands is most likely to form a high spin octahedral complex with cobalt(II)?
A)
CN
-
B)
NO
2
-
C)
I
-
D)
CO
E)
en
10
In the complex ion ML
6
n+
, M
n+
has four d electrons and L is a weak field ligand. According to crystal field theory the magnetic properties of this complex ion correspond to the presence of how many unpaired electrons?
A)
0
B)
1
C)
2
D)
3
E)
4
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