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Learning Objectives
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The objectives of Chapter 12 are to:

Develop fundamental relations between commonly encountered thermodynamic properties and express the properties that cannot be measured directly in terms of easily measurable properties.

Develop the Maxwell relations, which form the basis for many thermodynamic relations.

Develop the Clapeyron equation and determine the enthalpy of vaporization from P, v, and T measurements alone.

Develop general relations for cv, cp, du, dh, and ds that are valid for all pure substances.

Discuss the Joule-Thomson coefficient.

Develop a method of evaluating the Δh, Δu, and Δs of real gases through the use of generalized enthalpy and entropy departure charts.







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