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Chemistry, 7/e
Raymond Chang, Williams College
Chemical Bonding I: Basic Concepts
Self Assessment A
1
Which one of the following compounds is most likely to be ionic?
A)
HNF
2
B)
H
2
CO
C)
N
2
H
4
D)
CaCl
2
E)
ICl
2
Based on ionic radii and charges, which of the following solids would have the greatest lattice energy?
A)
SrO
B)
CsI
C)
MgCl
2
D)
KF
E)
NaF
3
In Ba(CN)
2
, the bonding is
A)
essentially ionic.
B)
essentially covalent.
C)
both ionic and covalent.
D)
neither ionic nor covalent.
4
Which of the following represents the most polar bond?
A)
B-C
B)
S-O
C)
C-O
D)
B-O
E)
C-C
5
Which of the Lewis structure(s) is(are) incorrect?
A)
(1.0K)
B)
(1.0K)
C)
(1.0K)
D)
(0.0K)
E)
C and D.
6
All of the following molecules contain only single bonds except
A)
H
2
O
2
B)
Cl
2
C)
CH
4
D)
H
2
O
E)
SO
2
7
The formal charge on the nitrogen atom in the nitrate ion is
A)
+2
B)
+1
C)
0
D)
-1
E)
-2
8
The sulfate ion is tetrahedral with four equal S-O distances of 149 pm. Which of the following is the most reasonable structure consistent with these facts?
A)
(0.0K)
B)
(0.0K)
C)
(0.0K)
D)
None of the above.
9
In which of the following species does the central atom violate the octet rule?
A)
CH
4
B)
SF
4
C)
PCl
4
+
D)
CCl
3
+
E)
NH
3
10
Estimate the enthalpy change for the reaction C
2
H
4
(g) + H
2
(g) ----> C
2
H
6
(g), given the following bond energies: BE(H-H) = 436 kJ/mol; BE(C-H) = 414 kJ/mol; BE(C-C) = 347 kJ/mol; BE(C=C) = 620 kJ/mol.
A)
-119 kJ
B)
+119 kJ
C)
-392 kJ
D)
+392 kJ
E)
None of the above.
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